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Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides

Konstantin Nikolaevich Shavrin 1
Konstantin Nikolaevich Shavrin
, 
Valentin Dmitrievich Gvozdev 1
Valentin Dmitrievich Gvozdev
, 
Serafim Vladimirovich Yurov 2
Serafim Vladimirovich Yurov
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1016/j.mencom.2008.01.007
Published 2008-01-14
Communication , Volume 18, Issue 1, 16-17
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Shavrin K. N. et al. Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 16-17.
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Shavrin K. N., Gvozdev V. D., Yurov S. V., Nefedov O. M. Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 16-17.
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TY - JOUR
DO - 10.1016/j.mencom.2008.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.007
TI - Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides
T2 - Mendeleev Communications
AU - Shavrin, Konstantin Nikolaevich
AU - Gvozdev, Valentin Dmitrievich
AU - Yurov, Serafim Vladimirovich
AU - Nefedov, Oleg Matveevich
PY - 2008
DA - 2008/01/14
PB - Mendeleev Communications
SP - 16-17
IS - 1
VL - 18
ER -
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@article{2008_Shavrin,
author = {Konstantin Nikolaevich Shavrin and Valentin Dmitrievich Gvozdev and Serafim Vladimirovich Yurov and Oleg Matveevich Nefedov},
title = {Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.007},
number = {1},
pages = {16--17},
doi = {10.1016/j.mencom.2008.01.007}
}
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Shavrin, Konstantin Nikolaevich, et al. “Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium monoalkylamides.” Mendeleev Communications, vol. 18, no. 1, Jan. 2008, pp. 16-17. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.007.

Abstract

Depending on the substituent at the triple bond, the reaction of 1-(alk-1-ynyl)-1-chlorocyclopropanes 1 with lithium monoalkylamides in THF gives hitherto unknown conjugated iminocyclopropenes 2 or 4-substituted 1,1-dimethylbuta-1,2-dienes 3 in up to 60% yields.

References