Abstract
Titania thin films modified with 0.5, 1.0 and 2.5 wt% ruthenium(III) chloride possess n-type semiconductor behaviour and enable the photofixation of dinitrogen to ammonia and nitrate in the presence of ethanol or humic acid.
References
1.
Schrauzer G.N., Guth T.D.
Journal of the American Chemical Society,
1977
2.
Rusina O., Eremenko A., Frank G., Strunk H.P., Kisch H.
Angewandte Chemie - International Edition,
2001
3.
Rusina O., Linnik O., Eremenko A., Kisch H.
Chemistry - A European Journal,
2003
4.
Linnik O., Kisch H.
Photochemical and Photobiological Sciences,
2006
5.
JCPDS (Joint Committee on Powder Diffraction Standards), 37-1227.
6.
Panić V.V., Dekanski A., Milonjić S.K., Atanasoski R.T., Nikolić B.Ž.
Colloids and Surfaces A: Physicochemical and Engineering Aspects,
1999
7.
Alam M.J., Cameron D.C.
Journal of Sol-Gel Science and Technology,
2002
8.
Wang J.A., Limas-Ballesteros R., López T., Moreno A., Gómez R., Novaro O., Bokhimi X.
Journal of Physical Chemistry B,
2001
9.
Rusina O., Macyk W., Kisch H.
Journal of Physical Chemistry B,
2005