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Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals

Usein Memetovich Dzhemilev ¹

Usein Memetovich Dzhemilev

0000-0002-7992-6337

¹ Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

10.1016/j.mencom.2008.01.001

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Published 2008-01-14

Focus article , Volume 18, Issue 1, 1-5

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Dzhemilev U. M. Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 1-5.

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Dzhemilev U. M. Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 1-5.

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TY - JOUR

DO - 10.1016/j.mencom.2008.01.001

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.001

TI - Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals

T2 - Mendeleev Communications

AU - Dzhemilev, Usein Memetovich

PY - 2008

DA - 2008/01/14

PB - Mendeleev Communications

SP - 1-5

IS - 1

VL - 18

ER -

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@article{2008_Dzhemilev,

author = {Usein Memetovich Dzhemilev},

title = {Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals},

journal = {Mendeleev Communications},

year = {2008},

volume = {18},

publisher = {Mendeleev Communications},

month = {Jan},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.001},

number = {1},

pages = {1--5},

doi = {10.1016/j.mencom.2008.01.001}

}

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Dzhemilev, Usein Memetovich. “Catalytic replacement of transition metal atoms in metallacarbocycles by the atoms of nontransition metals.” Mendeleev Communications, vol. 18, no. 1, Jan. 2008, pp. 1-5. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.001.

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Abstract

The phenomenon of catalytic replacement of transition metal atoms in metallacarbocycles by nontransition metal atoms to afford the corresponding organometallic compounds has been discovered and its mechanism is considered.

References

10.1016/S0065-3055(05)54004-8

Metallacycloalkanes – Synthesis, Structure and Reactivity of Medium to Large Ring Compounds

Blom B., Clayton H., Kilkenny M., Moss J.R.

Advances in Organometallic Chemistry, 2006

U. M. Dzhemilev, O. S. Vostrikova and G. A. Tolstikov, Fundamental Research in Homogeneous Catalysis, ed. A. E. Shilov, Gordon and Breach, New York, 1986, vol. 2 (Abstracts).

10.1016/S0022-328X(00)99674-8

Homogeneous zirconium based catalysts in organic synthesis

Dzhemilev U.M., Vostrikova O.S., Tolstikov G.A.

Journal of Organometallic Chemistry, 1986

10.1016/j.mencom.2008.01.001_bib4

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 1989

10.1016/0022-328X(94)88098-0

Transition metal complexes in the chemistry of vinylcyclopropanes

Khusnutdinov R.I., Dzhemilev U.M.

Journal of Organometallic Chemistry, 1994

10.1021/ja01482a026

New Unsaturated Heterocyclic Systems. I

Braye E.H., Hübel W., Caplier I.

Journal of the American Chemical Society, 1961

10.1021/ja00437a019

Synthesis and reactions of bis(cyclopentadienyl)titanium(IV) metallocycles

McDermott J.X., Wilson M.E., Whitesides G.M.

Journal of the American Chemical Society, 1976

10.1039/C39800000476

Metal complexes derived from the o-xylylidene ligand, o-C₆H₄(CH₂^–)₂, and the X-ray crystal and molecular structure of the metallocycle [Zr(η-C₅H₅)₂{(CH₂)₂C₆H₄-o}]

Lappert M.F., Martin T.R., Atwood J.L., Hunter W.E.

Journal of the Chemical Society Chemical Communications, 1980

10.1039/DT9840000399

Chemistry of o-xylidene–metal complexes. Part 2. Preparation and properties of the o-xylidene–metal(IV) complexes [M(CH₂C₆H₄CH₂-o)(η-C₅H₄R)₂](M = Ti, Zr, Hf, or Nb; R = H or SiMe₃) and [{M′(CH₂C₆H₄CH₂-o)₂(OC₄H₈)}_n](M′= Ti, Zr, or Hf); X-ray crystal structures of the metallaindanes [M(CH₂C₆H₄CH₂-o)(η-C₅H₄R)₂](R = H, M = Ti, Zr, or Hf; R = SiMe₃, M = Nb)

Bristow G.S., Lappert M.F., Martin T.R., Atwood J.L., Hunter W.F.

Journal of the Chemical Society Dalton Transactions, 1984

10.

10.1002/1521-3773(20000818)39:16<2950::AID-ANIE2950>3.0.CO;2-Y

Deoxygenative Cycloaddition of Aldehydes with Alkynes Mediated by AlCl3 and Zirconium: Formation of Cyclopentadiene Derivatives

Xi Z., Li P.

Angewandte Chemie - International Edition, 2000

11.

10.1002/1521-3765(20020916)8:18<4292::AID-CHEM4292>3.0.CO;2-G

Lewis Acid Mediated Reactions of Zirconacyclopentadienes with Aldehydes: One-Pot Synthetic Route to Indene and Cyclopentadiene Derivatives from Aldehydes and Benzyne or Alkynes

Zhao C., Li P., Cao X., Xi Z.

Chemistry - A European Journal, 2002

12.

10.1016/j.mencom.2008.01.001_bib12

Shur

J. Organomet. Chem., 1983

13.

10.1021/ja00475a058

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

Van Horn D.E., Negishi E.

Journal of the American Chemical Society, 1978

14.

10.1016/S0022-328X(00)84891-3

Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes

Van Horn D.E., Valente L.F., Idacavage M.J., Negishi E.

Journal of Organometallic Chemistry, 1978

15.

10.1021/ja00406a071

Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination

Yoshida T., Negishi E.

Journal of the American Chemical Society, 1981

16.

10.1002/9780471739876

Name Reactions and Reagents in Organic Synthesis

Mundy B.P., Ellerd M.G., Favaloro F.G.

2005

17.

10.1246/bcsj.80.233

Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis

Negishi E.

Bulletin of the Chemical Society of Japan, 2007

18.

10.1021/jo052157l

Direct Cyclopropanation of 1-Alkynylphosphonates by Cp₂ZrCl₂/2EtMgBr/2AlCl₃ To Afford Cyclopropylmethylphosphonates

Aziz Quntar A.A., Srebnik M.

Journal of Organic Chemistry, 2005

19.

10.1016/S0040-4020(03)00522-2

Reaction of aluminacyclopentadienes with aldehydes affording cyclopentadiene derivatives

Fang H., Zhao C., Li G., Xi Z.

Tetrahedron, 2003

20.

10.1016/j.mencom.2008.01.001_bib20

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 1983

21.

10.1016/0022-328X(85)87355-1

Some novelties in olefin carbometallation assisted by alkyl-magnesium and -aluminium derivatives and catalyzed by zirconium and titanium complexes

Dzhemilev U.M., Vostrikova O.S.

Journal of Organometallic Chemistry, 1985

22.

10.1016/S0040-4039(00)93606-2

A zirconium catalysed synthesis of 1,4-dimagnesium reagents.

Lewis D.P., Muller P.M., Whitby R.J., Jones R.V.

Tetrahedron Letters, 1991

23.

10.1016/j.mencom.2008.01.001_bib23

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 1979

24.

10.1016/j.mencom.2008.01.001_bib24

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 1985

25.

10.1016/j.mencom.2008.01.001_bib25

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 1990

26.

10.1070/RC1990v059n12ABEH003584

Catalysis by metal complexes in organoaluminium synthesis

Dzhemilev U.M., Vostrikova O.S., Tolstikov G.A.

Russian Chemical Reviews, 1990

27.

10.1016/j.mencom.2008.01.001_bib27

Dzhemilev

Metalloorg. Khim., 1992

28.

10.1063/1.1576212

Electronic structure of the π-bonded Al–C2H4 complex: Characterization of the ground and low-lying excited states

Cristian A.C., Krylov A.I.

Journal of Chemical Physics, 2003

29.

10.1016/j.mencom.2008.01.001_bib28_2

Dewar

Bull. Soc. Chim. Fr., 1951

30.

10.1039/jr9530002939

586. Olefin co-ordination compounds. Part III. Infra-red spectra and structure: attempted preparation of acetylene complexes

Chatt J., Duncanson L.A.

Journal of the Chemical Society (Resumed), 1953

31.

10.1070/MC1992v002n01ABEH000109

Regio- and Stereo-selective Synthesis of trans-3,4-Dialkyl-substituted Aluminacyclopentanes in the Presence of (η5-C5H5)2ZrCl2

Dzhemilev U.M., Ibragimov A.G., Morozov A.B.

Mendeleev Communications, 1992

32.

10.1016/0022-328X(94)88022-0

Regio- and stereoselective synthesis for a novel class of organoaluminium compounds — substituted aluminacyclopentanes and aluminacyclopentenes assis

Dzhemilev U.M., Ibragimov A.G.

Journal of Organometallic Chemistry, 1994

33.

10.1016/0040-4020(94)01123-H

New achievements in the use of zirconium complexes in the chemistry of organo-aluminium and magnesium compounds

Dzhemilev U.M.

Tetrahedron, 1995

34.

10.1070/MC1997v007n05ABEH000791

The first example of synthesis of aluminacyclopropanes catalysed by (η5-C5H5)2TiCl2

Dzhemilev U.M., Ibragimov A.G., Khafizova L.O., Rusakov S.V., Khalilov L.M.

Mendeleev Communications, 1997

35.

10.1016/j.mencom.2008.01.001_bib33

Ibragimov

Izv. Akad. Nauk SSSR, Ser. Khim., 2002

36.

10.1016/j.mencom.2008.01.001_bib34

Dzhemilev

Izv. Akad. Nauk SSSR, Ser. Khim., 2001

37.

10.1016/j.mencom.2008.01.001_bib35

Dzhemilev

Zh. Org. Khim., 2005

38.

10.1016/j.mencom.2008.01.001_bib36

Dzhemilev

Izv. Akad. Nauk, Ser. Khim., 1997

39.

10.1021/ja00170a001

Aluminirene (HAlC2H2) and aluminirane (HAlC2H4): aluminum-substituted counterparts of cyclopropene and cyclopropane

Xie Y., Schaefer H.F.

Journal of the American Chemical Society, 1990

40.

10.1021/ja057731p

Aluminacyclopropene: Syntheses, Characterization, and Reactivity toward Terminal Alkynes

Zhu H., Oswald R.B., Fan H., Roesky H.W., Ma Q., Yang Z., Schmidt H., Noltemeyer M., Starke K., Hosmane N.S.

Journal of the American Chemical Society, 2006

41.

10.1070/RC2000v069n02ABEH000519

Metal complex catalysis in the synthesis of organoaluminium compounds

Dzhemilev U.M., Ibragimov A.G.

Russian Chemical Reviews, 2000

42.

10.1016/j.mencom.2008.01.001_bib40

Khalilov

Izv. Akad. Nauk, Ser. Khim., 2000