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Synthesis of enantiopure 1,3,4-thiazaphospholes

Ludmila Konstantinovna Kibardina 1
Ludmila Konstantinovna Kibardina
, 
Michael Arkad'evich Pudovik 1
Michael Arkad'evich Pudovik
, 
Vladimir Alekseevich Alfonsov 1
Vladimir Alekseevich Alfonsov
, 
Olga Nikolaevna Kataeva 1
Olga Nikolaevna Kataeva
10.1016/j.mencom.2007.11.007
Published 2007-11-09
Communication , Volume 17, Issue 6, 323-324
1
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Kibardina L. K. et al. Synthesis of enantiopure 1,3,4-thiazaphospholes // Mendeleev Communications. 2007. Vol. 17. No. 6. pp. 323-324.
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Kibardina L. K., Pudovik M. A., Alfonsov V. A., Kataeva O. N. Synthesis of enantiopure 1,3,4-thiazaphospholes // Mendeleev Communications. 2007. Vol. 17. No. 6. pp. 323-324.
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TY - JOUR
DO - 10.1016/j.mencom.2007.11.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.11.007
TI - Synthesis of enantiopure 1,3,4-thiazaphospholes
T2 - Mendeleev Communications
AU - Kibardina, Ludmila Konstantinovna
AU - Pudovik, Michael Arkad'evich
AU - Alfonsov, Vladimir Alekseevich
AU - Kataeva, Olga Nikolaevna
PY - 2007
DA - 2007/11/09
PB - Mendeleev Communications
SP - 323-324
IS - 6
VL - 17
ER -
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@article{2007_Kibardina,
author = {Ludmila Konstantinovna Kibardina and Michael Arkad'evich Pudovik and Vladimir Alekseevich Alfonsov and Olga Nikolaevna Kataeva},
title = {Synthesis of enantiopure 1,3,4-thiazaphospholes},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.11.007},
number = {6},
pages = {323--324},
doi = {10.1016/j.mencom.2007.11.007}
}
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Kibardina, Ludmila Konstantinovna, et al. “Synthesis of enantiopure 1,3,4-thiazaphospholes.” Mendeleev Communications, vol. 17, no. 6, Nov. 2007, pp. 323-324. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.11.007.

Keywords

Cyclization reaction
diastereoselectivity
Racemic and R-(+)-N-trimethylsilyl-(1-phenyl)ethylamines
Thiazaphosphole

Abstract

Racemic and (R)-(+)-N-trimethylsilyl-(1-phenyl)ethylamines stereoselectively react with O-phenylchloromethylisothiocyanatothiophosphonate to give a diastereomeric mixture of separable 1,3,4-thiazaphospholes; racemic thiazaphosphole crystallises as a conglomerate.

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Trichlorosilane reduction of some diazaphospholene oxides
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