Home / Publications / Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine

Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine

7
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Chapyshev S. V. Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine // Mendeleev Communications. 2007. Vol. 17. No. 5. pp. 287-288.
GOST all authors (up to 50) Copy
Chapyshev S. V. Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine // Mendeleev Communications. 2007. Vol. 17. No. 5. pp. 287-288.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2007.09.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.013
TI - Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine
T2 - Mendeleev Communications
AU - Chapyshev, Sergei Viktorovich
PY - 2007
DA - 2007/09/12
PB - Mendeleev Communications
SP - 287-288
IS - 5
VL - 17
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Chapyshev,
author = {Sergei Viktorovich Chapyshev},
title = {Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.013},
number = {5},
pages = {287--288},
doi = {10.1016/j.mencom.2007.09.013}
}
MLA
Cite this
MLA Copy
Chapyshev, Sergei Viktorovich. “Nucleophilic replacement of the azido groups by amines in 2,4,6-triazido-3-chloro-5-cyanopyridine.” Mendeleev Communications, vol. 17, no. 5, Sep. 2007, pp. 287-288. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.013.

Abstract

2,4,6-Triazido-3-chloro-5-cyanopyridine reacts with pyrrolidine and piperidine to form corresponding 2-azido-4,6-diamino-3-chloro-5-cyanopyridines in high yields.

References

1.
Azides and Nitrenes. Reactivity and Utility, ed. E. F. V. Scriven, Academic Press, New York, 1984.
2.
Azides: their preparation and synthetic uses
Scriven E.F., Turnbull K.
Chemical Reviews, 1988
3.
Organic Azides: An Exploding Diversity of a Unique Class of Compounds
Bräse S., Gil C., Knepper K., Zimmermann V.
Angewandte Chemie - International Edition, 2005
4.
10.1016/j.mencom.2007.09.013_bib2_1
Chapyshev
Khim. Geterotsikl. Soedin., 1993
6.
10.1016/j.mencom.2007.09.013_bib2_3
Chapyshev
Khim. Geterotsikl. Soedin., 1997
8.
10.1016/j.mencom.2007.09.013_bib3_1
Chapyshev
Khim. Geterotsikl. Soedin., 1996
9.
10.1016/j.mencom.2007.09.013_bib3_2
Chapyshev
Khim. Geterotsikl. Soedin., 2000
10.
10.1016/j.mencom.2007.09.013_bib3_3
Chapyshev
Khim. Geterotsikl. Soedin., 2001
12.
13.
Mono-, Di-, and Trinitrenes in the Pyridine Series
Chapyshev S.V., Kuhn A., Wong M.W., Wentrup C.
Journal of the American Chemical Society, 2000
14.
Quintet and Septet State Systems Based on Pyridylnitrenes:  Effects of Substitution on Open-Shell High-Spin States
Chapyshev S.V., Walton R., Sanborn J.A., Lahti P.M.
Journal of the American Chemical Society, 2000
16.
Quintet State Electron Spin Resonance Spectra of Pyridyldinitrenes
Chapyshev S.V., Walton R., Serwinski P.R., Lahti P.M.
Journal of Physical Chemistry A, 2004
17.
Zero-field splitting parameters of quintet 2,6-dinitrenopyridines
Chapyshev S.V., Lahti P.M.
Journal of Physical Organic Chemistry, 2006
18.
Chapter 6. Nitrile reactivity
Schaefer F.C.
Chemistry of Functional Groups, 1970
19.
J.A. Gautier, M. Miocque and C.C. Farnoux, in The Chemistry of Amidines and Imidates, ed. S. Patai, Interscience, New York, 1975, ch. 7, pp. 283–348.
22.
Polyhalogenoaromatic compounds. Part 48. Reactions of tetrachioro-4-cyanopyridine with mono- and di-functional nucleophiles
Dainter R.S., Julia L., Suschitzky H., Wakefield B.J.
Journal of the Chemical Society Perkin Transactions 1, 1982
23.
Polyhalogenoaromatic compounds. Part 49. Synthesis of carbolines by the reaction of enamines with tetrachloro-4-cyanopyridine
Suschitzky H., Wakefield B.J., Walocha K., Hughes N., Nelson A.J.
Journal of the Chemical Society Perkin Transactions 1, 1983
24.
10.1016/j.mencom.2007.09.013_bib9_4
Chapyshev
Khim. Geterotsikl. Soedin., 1991