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New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent

Artem Igorevich Vedernikov 1
Artem Igorevich Vedernikov
, 
Dmitry V Kondratuk 1
Dmitry V Kondratuk
, 
Natalia Anatol'evna Lobova 1
Natalia Anatol'evna Lobova
, 
Tatyana Mikhailovna Valova 1
Tatyana Mikhailovna Valova
, 
Valerii Aleksandrovich Barachevskiĭ 1
Valerii Aleksandrovich Barachevskiĭ
, 
Mikhail Vladimirovich Alfimov 1
Mikhail Vladimirovich Alfimov
, 
Sergei Panteleimonovich Gromov 1
Sergei Panteleimonovich Gromov
10.1016/j.mencom.2007.09.005
Published 2007-09-12
Communication , Volume 17, Issue 5, 264-267
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Vedernikov A. I. et al. New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent // Mendeleev Communications. 2007. Vol. 17. No. 5. pp. 264-267.
GOST all authors (up to 50) Copy
Vedernikov A. I., Kondratuk D. V., Lobova N. A., Valova T. M., Barachevskiĭ V. A., Alfimov M. V., Gromov S. P. New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent // Mendeleev Communications. 2007. Vol. 17. No. 5. pp. 264-267.
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TY - JOUR
DO - 10.1016/j.mencom.2007.09.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.005
TI - New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent
T2 - Mendeleev Communications
AU - Vedernikov, Artem Igorevich
AU - Kondratuk, Dmitry V
AU - Lobova, Natalia Anatol'evna
AU - Valova, Tatyana Mikhailovna
AU - Barachevskiĭ, Valerii Aleksandrovich
AU - Alfimov, Mikhail Vladimirovich
AU - Gromov, Sergei Panteleimonovich
PY - 2007
DA - 2007/09/12
PB - Mendeleev Communications
SP - 264-267
IS - 5
VL - 17
ER -
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@article{2007_Vedernikov,
author = {Artem Igorevich Vedernikov and Dmitry V Kondratuk and Natalia Anatol'evna Lobova and Tatyana Mikhailovna Valova and Valerii Aleksandrovich Barachevskiĭ and Mikhail Vladimirovich Alfimov and Sergei Panteleimonovich Gromov},
title = {New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.005},
number = {5},
pages = {264--267},
doi = {10.1016/j.mencom.2007.09.005}
}
MLA
Cite this
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Vedernikov, Artem Igorevich, et al. “New cation-‘capped’ complex of the Z-isomer of a crown-containing styryl dye bearing a long N-ammonioalkyl substituent.” Mendeleev Communications, vol. 17, no. 5, Sep. 2007, pp. 264-267. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.09.005.

Keywords

cation-‘capped’ complex
crown ether
E–Z-photoisomerisation
hydrogen bonding
styryl dye

Abstract

Two new styryl dyes of the benzothiazole series containing a 18-crown-6 moiety and an N-ammoniohexyl or N-ethyl substituent were synthesised. In acetonitrile, the dye bearing the ammoniohexyl linker forms a stable dimeric complex in the E-form and an intramolecular cation-‘capped’ complex in the Z-form due to ‘host–guest’ hydrogen bonding.

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