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Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes

Yuri Grigor'evich Gololobov 1
Yuri Grigor'evich Gololobov
, 
Olesya Aleksandrovna Linchenko 1
Olesya Aleksandrovna Linchenko
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
,  , 
Irina Aleksandrovna Garbuzova 1
Irina Aleksandrovna Garbuzova
10.1016/j.mencom.2007.06.017
Published 2007-06-22
Communication , Volume 17, Issue 4, 232-233
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Gololobov Y. G. et al. Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 232-233.
GOST all authors (up to 50) Copy
Gololobov Y. G., Linchenko O. A., Petrovskii P. V., Khrustalev V. N., Garbuzova I. A. Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 232-233.
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TY - JOUR
DO - 10.1016/j.mencom.2007.06.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.017
TI - Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes
T2 - Mendeleev Communications
AU - Gololobov, Yuri Grigor'evich
AU - Linchenko, Olesya Aleksandrovna
AU - Petrovskii, Pavel Vasil'evich
AU - Khrustalev, Victor Nikolaevich
AU - Garbuzova, Irina Aleksandrovna
PY - 2007
DA - 2007/06/22
PB - Mendeleev Communications
SP - 232-233
IS - 4
VL - 17
ER -
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@article{2007_Gololobov,
author = {Yuri Grigor'evich Gololobov and Olesya Aleksandrovna Linchenko and Pavel Vasil'evich Petrovskii and Victor Nikolaevich Khrustalev and Irina Aleksandrovna Garbuzova},
title = {Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.017},
number = {4},
pages = {232--233},
doi = {10.1016/j.mencom.2007.06.017}
}
MLA
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Gololobov, Yuri Grigor'evich, et al. “Dual reactivity of the phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate toward 2,4-dinitro- and 2,4,6-trinitrofluorobenzenes.” Mendeleev Communications, vol. 17, no. 4, Jun. 2007, pp. 232-233. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.017.

Abstract

A phosphonium zwitterion formed by the reaction of triisopropylphosphine with ethyl 2-cyanoacrylate possesses a dual reactivity: while this ion reacts with 2,4-dinitrofluorobenzene as a C-nucleophile, it reacts with 2,4,6-trinitrofluorobenzene as an N-nucleophile.

References

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