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Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation

Felix Dmitrievich Sokolov 1
Felix Dmitrievich Sokolov
, 
Sergey Valer'evich Baranov 1
Sergey Valer'evich Baranov
, 
Nail Galievich Zabirov 1
Nail Galievich Zabirov
, 
Dmitry Borisovich Krivolapov 2
Dmitry Borisovich Krivolapov
, 
Igor Anatol'evich Litvinov 2
Igor Anatol'evich Litvinov
, 
Boulat Imamutdinovich Khairutdinov 1
Boulat Imamutdinovich Khairutdinov
, 
Rafael Askhatovich Cherkasov 1
Rafael Askhatovich Cherkasov
10.1016/j.mencom.2007.06.013
Published 2007-06-22
Communication , Volume 17, Issue 4, 222-223
17
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Sokolov F. D. et al. Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 222-223.
GOST all authors (up to 50) Copy
Sokolov F. D., Baranov S. V., Zabirov N. G., Krivolapov D. B., Litvinov I. A., Khairutdinov B. I., Cherkasov R. A. Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 222-223.
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TY - JOUR
DO - 10.1016/j.mencom.2007.06.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.013
TI - Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation
T2 - Mendeleev Communications
AU - Sokolov, Felix Dmitrievich
AU - Baranov, Sergey Valer'evich
AU - Zabirov, Nail Galievich
AU - Krivolapov, Dmitry Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Khairutdinov, Boulat Imamutdinovich
AU - Cherkasov, Rafael Askhatovich
PY - 2007
DA - 2007/06/22
PB - Mendeleev Communications
SP - 222-223
IS - 4
VL - 17
ER -
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@article{2007_Sokolov,
author = {Felix Dmitrievich Sokolov and Sergey Valer'evich Baranov and Nail Galievich Zabirov and Dmitry Borisovich Krivolapov and Igor Anatol'evich Litvinov and Boulat Imamutdinovich Khairutdinov and Rafael Askhatovich Cherkasov},
title = {Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.013},
number = {4},
pages = {222--223},
doi = {10.1016/j.mencom.2007.06.013}
}
MLA
Cite this
MLA Copy
Sokolov, Felix Dmitrievich, et al. “Unusual structure of an N-phosphoryl-N’-isopropylthiourea chelate with the nickel(II) cation.” Mendeleev Communications, vol. 17, no. 4, Jun. 2007, pp. 222-223. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.013.

Abstract

The reaction of the potassium salt of N-phosphorylated thiourea PriN'HC(S)NHP(O)(OPri)2 (HL) with the NiII cation leads to the complex [NiL2(HL)2]; according to X-ray analysis, two neutral HL molecules are coordinated in the second sphere of the planar 1,3-N,S-chelate [NiL2] via (HL) PNH···O=P (NiL2) hydrogen bonds.

References

1.
Competitive coordination: ambident ligands in the modern chemistry of metal complexes
Garnovskii A.D., Garnovskii D.A., Vasil'chenko I.S., Burlov A.S., Sadimenko A.P., Sadekov I.D.
Russian Chemical Reviews, 1997
2.
L. M. Blanco, A. D. Garnovskii, D. A. Garnovskii, B. I. Kharisov, M. A. Mendez-Rojas and I. S. Vasilchenko in Synthetic Coordination and Organometallic Chemistry, eds. A. D. Garnovskii and B. I. Kharisov, Marcel Dekker, New York–Basel, 2003.
3.
Coordination diversity of N-phosphoryl-N′-phenylthiourea (LH) towards CoII, NiII and PdII cations: Crystal structure of ML2-N,S and ML2-O,S chelates
Sokolov F.D., Zabirov N.G., Yamalieva L.N., Shtyrlin V.G., Garipov R.R., Brusko V.V., Verat A.Y., Baranov S.V., Mlynarz P., Glowiak T., Kozlowski H.
Inorganica Chimica Acta, 2006
4.
Combined EPR and DFT study of the copper(II) complexes with N-phosphoryl thioureas
Garipov R.R., Shtyrlin V.G., Safin D.A., Zyavkina Y.I., Sokolov F.D., Konkin A.L., Aganov A.V., Zakharov A.V.
Chemical Physics, 2006
6.
10.1016/j.mencom.2007.06.013_bib3_2
Skopenko
Usp. Khim., 2004
7.
N-Acylamidophosphinates: Structure, Properties and Complexation Towards Main Group Metal Cations
Sokolov F., Brusko V., Zabirov N., Cherkasov R.
Current Organic Chemistry, 2005
8.
Studies on cobalt(II) complexes with N-thioacylamido(thio)phosphates: X-ray crystal structure of the Co[PhC(S)NP(S)(OPri)2]2
Safin D.A., Sokolov F.D., Zabirov N.G., Brusko V.V., Krivolapov D.B., Litvinov I.A., Luckay R.C., Cherkasov R.A.
Polyhedron, 2006
9.
10.1016/j.mencom.2007.06.013_bib5
Sokolov
Zh. Obshch. Khim., 2005
10.
Sokolov F.D., Safin D.A., Zabirov N.G., Yamalieva L.N., Krivolapov D.B., Litvinov I.A.
Mendeleev Communications, 2004
11.
E-map improvement in direct procedures
Altomare A., Cascarano G., Giacovazzo C., Viterbo D.
Acta Crystallographica Section A Foundations of Crystallography, 1991
12.
WinGXsuite for small-molecule single-crystal crystallography
Farrugia L.J.
Journal of Applied Crystallography, 1999
13.
L. H. Straver and A. J. Schierbeek, MoLEN. Structure Determination System, Nonius B.V. Delft, The Netherlands, 1994, vols. 1, 2.
14.
10.1016/j.mencom.2007.06.013_bib10
Spek
Acta Crystallogr., Sect. A, 1990