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Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine

Victor Evgen'evich Pushkarev ¹

Victor Evgen'evich Pushkarev

Maria O Breusova ¹

Maria O Breusova

Sergey Evgen'evich Nefedov ²

Sergey Evgen'evich Nefedov

Larisa Godvigovna Tomilova ¹

Larisa Godvigovna Tomilova

¹ Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

² N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2007.06.012

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Published 2007-06-22

Communication , Volume 17, Issue 4, 220-221

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Pushkarev V. E. et al. Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 220-221.

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Pushkarev V. E., Breusova M. O., Nefedov S. E., Tomilova L. G. Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine // Mendeleev Communications. 2007. Vol. 17. No. 4. pp. 220-221.

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TY - JOUR

DO - 10.1016/j.mencom.2007.06.012

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.012

TI - Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine

T2 - Mendeleev Communications

AU - Pushkarev, Victor Evgen'evich

AU - Breusova, Maria O

AU - Nefedov, Sergey Evgen'evich

AU - Tomilova, Larisa Godvigovna

PY - 2007

DA - 2007/06/22

PB - Mendeleev Communications

SP - 220-221

IS - 4

VL - 17

ER -

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@article{2007_Pushkarev,

author = {Victor Evgen'evich Pushkarev and Maria O Breusova and Sergey Evgen'evich Nefedov and Larisa Godvigovna Tomilova},

title = {Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine},

journal = {Mendeleev Communications},

year = {2007},

volume = {17},

publisher = {Mendeleev Communications},

month = {Jun},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.012},

number = {4},

pages = {220--221},

doi = {10.1016/j.mencom.2007.06.012}

}

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Pushkarev, Victor Evgen'evich, et al. “Synthesis and structure of europium(III) double- and triple-decker complexes with 2,3,9,10,16,17,23,24-octabutylphthalocyanine.” Mendeleev Communications, vol. 17, no. 4, Jun. 2007, pp. 220-221. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.06.012.

Abstract

The reaction of 4,5-dibutylphthalodinitrile with Eu(acac)₃·3H₂O at 130 °C results in sandwich-type bis[2,3,9,10,16,17,23,24- octabutylphthalocyaninato]europium(III) 1 and the reaction of free 2,3,9,10,16,17,23,24-octabutylphthalocyanine with Eu(acac)₃·3H₂O at 196 °C gives tris[2,3,9,10,16,17,23,24-octabutylphthalocyaninato]dieuropium(III) 2. Structures of compounds 1 and 2 have been determined using X-ray diffraction analysis, electronic and NMR spectroscopy and mass spectrometry.

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