Home / Publications / Synthesis and molecular structure of seven isomers of C70(C2F5)10

Synthesis and molecular structure of seven isomers of C70(C2F5)10

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
10.1016/j.mencom.2007.05.014
Published 2007-05-03
Communication , Volume 17, Issue 3, 172-174
19
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Tamm N. B., Troyanov S. I. Synthesis and molecular structure of seven isomers of C70(C2F5)10 // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 172-174.
GOST all authors (up to 50) Copy
Tamm N. B., Troyanov S. I. Synthesis and molecular structure of seven isomers of C70(C2F5)10 // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 172-174.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2007.05.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.014
TI - Synthesis and molecular structure of seven isomers of C70(C2F5)10
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2007
DA - 2007/05/03
PB - Mendeleev Communications
SP - 172-174
IS - 3
VL - 17
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Tamm,
author = {Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {Synthesis and molecular structure of seven isomers of C70(C2F5)10},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.014},
number = {3},
pages = {172--174},
doi = {10.1016/j.mencom.2007.05.014}
}
MLA
Cite this
MLA Copy
Tamm, Nadezhda Borisovna, and Sergey Igorevich Troyanov. “Synthesis and molecular structure of seven isomers of C70(C2F5)10.” Mendeleev Communications, vol. 17, no. 3, May. 2007, pp. 172-174. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.014.

Abstract

A mixture of C70(C2F5)n (n = 8, 10, 12) compounds was synthesised by a reaction of C70 with C2F5I at 350 °C followed by HPLC separation; crystal structure determination for seven isomers of C70(C2F5)10 revealed a large variety of addition patterns most of which are unprecedented in the regiochemistry of [70]fullerene.

References

1.
Unusual addition patterns in trifluoromethylation of [60]fullerene
Darwish A.D., Abdul-Sada A.K., Avent A.G., Lyakhovetsky Y., Shilova E.A., Taylor R.
Organic and Biomolecular Chemistry, 2003
2.
Production of Perfluoroalkylated Nanospheres from Buckminsterfullerene
Fagan P.J., Krusic P.J., McEwen C.N., Lazar J., Parkert D.H., Herron N., Wasserman E.
Science, 1993
3.
10.1016/j.mencom.2007.05.014_bib3
Uzkikh
Dokl. Akad. Nauk, 2001
4.
10.1016/j.mencom.2007.05.014_bib4
Troyanov
J. Fluorine Chem., 2007
5.
Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18
Avdoshenko S.M., Goryunkov A.A., Ioffe I.N., Ignat'eva D.V., Sidorov L.N., Pattison P., Kemnitz E., Troyanov S.I.
Chemical Communications, 2006
6.
Synthesis and structures of poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6and 1,6,11,18,24,27,32,35-C60(C2F5)8
Kareev I.E., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Strauss S.H., Boltalina O.V.
Chemical Communications, 2006
7.
10.1016/j.mencom.2007.05.014_bib7
Ignat’eva
Chem. Commun., 1778
8.
Preparation, Crystallographic Characterization, and Theoretical Study of C70(CF3)14
Goryunkov A.A., Ignat’eva D.V., Tamm N.B., Moiseeva N.N., Ioffe I.N., Avdoshenko S.M., Markov V.Y., Sidorov L.N., Kemnitz E., Troyanov S.I.
European Journal of Organic Chemistry, 2006
9.
Advances in direct methods for protein crystallography.
Usón I., Sheldrick G.M.
Current Opinion in Structural Biology, 1999
10.
G. M. Sheldrick, SHELXL97. Program for Crystal Structure Refinement, Universität Göttingen, Germany, 1997.
11.
Numbering of Fullerenes (IUPAC Recommendations 2004)
Cozzi F., Powell W.H., Thilgen C.
Pure and Applied Chemistry, 2005
12.
High-Temperature Synthesis of the Surprisingly StableC1-C70(CF3)10 Isomer with apara7-meta-para Ribbon of Nine C6(CF3)2 Edge-Sharing Hexagons
Kareev I.E., Kuvychko I.V., Popov A.A., Lebedkin S.F., Miller S.M., Anderson O.P., Strauss S.H., Boltalina O.V.
Angewandte Chemie - International Edition, 2005
13.
Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage.
Troshin P.A., Lyubovskaya R.N., Ioffe I.N., Shustova N.B., Kemnitz E., Troyanov S.I.
Angewandte Chemie - International Edition, 2005
14.
A model for pathways of radical addition to fullerenes
Rogers K.M., Fowler P.W.
Chemical Communications, 1999
15.
‘Fluorine dance’ on the fullerene surface
Gakh A.A., Tuinman A.A.
Tetrahedron Letters, 2001
16.
Preparation and Structural Characterization of Two Kinetically Stable Chlorofullerenes, C60Cl28 and C60Cl30
Troyanov S.I., Shustova N.B., Popov A.A., Sidorov L.N., Kemnitz E.
Angewandte Chemie - International Edition, 2005
17.
Goryunkov A.A., Dorozhkin E.I., Tamm N.B., Ignat’eva D.V., Avdoshenko S.M., Sidorov L.N., Troyanov S.I.
Mendeleev Communications, 2007
18.
10.1016/j.mencom.2007.05.014_bib18
Kareev
Acta Crystallogr., 2006