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Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines

Vitaly Yur'evich Fedorenko 1
Vitaly Yur'evich Fedorenko
, 
Rustam N Baryshnikov 1
Rustam N Baryshnikov
, 
Rusalia Maskhutovna Vafina 1
Rusalia Maskhutovna Vafina
,  , 
Evgenii Naumovich Klimovitskii 1
Evgenii Naumovich Klimovitskii
10.1016/j.mencom.2007.05.013
Published 2007-05-03
Communication , Volume 17, Issue 3, 170-171
5
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Fedorenko V. Y. et al. Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 170-171.
GOST all authors (up to 50) Copy
Fedorenko V. Y., Baryshnikov R. N., Vafina R. M., Shtyrlin Y. G., Klimovitskii E. N. Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 170-171.
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TY - JOUR
DO - 10.1016/j.mencom.2007.05.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.013
TI - Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines
T2 - Mendeleev Communications
AU - Fedorenko, Vitaly Yur'evich
AU - Baryshnikov, Rustam N
AU - Vafina, Rusalia Maskhutovna
AU - Shtyrlin, Yurii Grigor'evich
AU - Klimovitskii, Evgenii Naumovich
PY - 2007
DA - 2007/05/03
PB - Mendeleev Communications
SP - 170-171
IS - 3
VL - 17
ER -
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@article{2007_Fedorenko,
author = {Vitaly Yur'evich Fedorenko and Rustam N Baryshnikov and Rusalia Maskhutovna Vafina and Yurii Grigor'evich Shtyrlin and Evgenii Naumovich Klimovitskii},
title = {Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.013},
number = {3},
pages = {170--171},
doi = {10.1016/j.mencom.2007.05.013}
}
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Fedorenko, Vitaly Yur'evich, et al. “Facial selectivity in the reaction of dihalocarbenes with 2-substituted 4,7-dihydro-1,3-dioxepines.” Mendeleev Communications, vol. 17, no. 3, May. 2007, pp. 170-171. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.013.

Abstract

The dichloro(dibromo)cyclopropanation of conformationally heterogeneous 2-substituted 4,7-dihydro-1,3-dioxepines was found to afford a low selectivity; endo addition on the side of a remote alkyl substitutent is governed by the π-facial solvation of substrates.

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