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Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination

Aleksei Gennadievich Sergeev 1
Aleksei Gennadievich Sergeev
, 
Galina Anisimovna Artamkina 1
Galina Anisimovna Artamkina
,  , 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
, 
10.1016/j.mencom.2007.05.003
Published 2007-05-03
Communication , Volume 17, Issue 3, 142-144
6
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Sergeev A. G. et al. Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 142-144.
GOST all authors (up to 50) Copy
Sergeev A. G., Artamkina G. A., Khrustalev V. N., Antipin M. Y., Beletskaya I. P. Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 142-144.
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TY - JOUR
DO - 10.1016/j.mencom.2007.05.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.003
TI - Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination
T2 - Mendeleev Communications
AU - Sergeev, Aleksei Gennadievich
AU - Artamkina, Galina Anisimovna
AU - Khrustalev, Victor Nikolaevich
AU - Antipin, Mikhail Yuvenal'evich
AU - Beletskaya, Irina Petrovna
PY - 2007
DA - 2007/05/03
PB - Mendeleev Communications
SP - 142-144
IS - 3
VL - 17
ER -
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@article{2007_Sergeev,
author = {Aleksei Gennadievich Sergeev and Galina Anisimovna Artamkina and Victor Nikolaevich Khrustalev and Mikhail Yuvenal'evich Antipin and Irina Petrovna Beletskaya},
title = {Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.003},
number = {3},
pages = {142--144},
doi = {10.1016/j.mencom.2007.05.003}
}
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Sergeev, Aleksei Gennadievich, et al. “Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination.” Mendeleev Communications, vol. 17, no. 3, May. 2007, pp. 142-144. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.003.

Abstract

Arylamidate palladium complexes containing deprotonated p-methylbenzamide and phthalimide have been synthesised; the latter has been characterised by X-ray diffraction data. A comparison of the catalytic and stoichiometric versions of N-arylation of p-methylbenzamide and phthalimide in the presence of palladium complexes and DPPF as a ligand has been carried out.

References

1.
J. F. Hartwig, in Handbook of Organopalladium Chemistry for Organic Synthesis, ed. E.-I. Negishi, Wiley, New York, 2002, vol. 1, pp. 1051–1096.
4.
Palladium-catalyzed reaction of aryl halides with ureas
Artamkina G.A., Sergeev A.G., Beletskaya I.P.
Tetrahedron Letters, 2001
6.
10.1016/j.mencom.2007.05.003_bib6
Sergeev
Zh. Org. Khim., 2005
7.
Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes
Shekhar S., Ryberg P., Hartwig J.F., Mathew J.S., Blackmond D.G., Strieter E.R., Buchwald S.L.
Journal of the American Chemical Society, 2006
12.
Mechanism of Aryl Chloride Amination:  Base-Induced Oxidative Addition
Alcazar-Roman L.M., Hartwig J.F.
Journal of the American Chemical Society, 2001
16.
Organometallic Chemistry of Amidate Complexes. Accelerating Effect of Bidentate Ligands on the Reductive Elimination of N-Aryl Amidates from Palladium(II)
Fujita K., Yamashita M., Puschmann F., Alvarez-Falcon M.M., Incarvito C.D., Hartwig J.F.
Journal of the American Chemical Society, 2006
17.
G. M. Sheldrick, SADABS, V2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS Inc., Madison, WI, 1998.
18.
G. M. Sheldrick, SHELXTL, V5.10, Bruker AXS Inc., Madison, WI, 1998.
26.
Equilibrium acidities in dimethyl sulfoxide solution
Bordwell F.G.
Accounts of Chemical Research, 1988