Home / Publications / Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt

Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt

Hermann J Frohn 1
Hermann J Frohn
, 
Vadim Victorovich Bardin 2
Vadim Victorovich Bardin
10.1016/j.mencom.2007.05.001
Published 2007-05-03
Communication , Volume 17, Issue 3, 137-138
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Frohn H. J., Bardin V. V. Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 137-138.
GOST all authors (up to 50) Copy
Frohn H. J., Bardin V. V. Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt // Mendeleev Communications. 2007. Vol. 17. No. 3. pp. 137-138.
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TY - JOUR
DO - 10.1016/j.mencom.2007.05.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.001
TI - Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt
T2 - Mendeleev Communications
AU - Frohn, Hermann J
AU - Bardin, Vadim Victorovich
PY - 2007
DA - 2007/05/03
PB - Mendeleev Communications
SP - 137-138
IS - 3
VL - 17
ER -
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@article{2007_Frohn,
author = {Hermann J Frohn and Vadim Victorovich Bardin},
title = {Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.001},
number = {3},
pages = {137--138},
doi = {10.1016/j.mencom.2007.05.001}
}
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Frohn, Hermann J., and Vadim Victorovich Bardin. “Distinct reactivities of cis- and trans-RFCF=CFBF2 towards XeF2 and the first synthesis of a [trans-RFCF=CFXe]+ salt.” Mendeleev Communications, vol. 17, no. 3, May. 2007, pp. 137-138. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.05.001.

Abstract

The competitive reaction of C4F9CF=CFBF2 (cis : trans = 1.2:1) with XeF2 demonstrated for the first time a remarkably lower reaction rate of the trans isomer with respect to the cis isomer in the xenodeborylation reaction (formation of the [C4F9CF=CFXe]+ cation with a cis : trans ratio of 2.5 to 4:1) and allowed us to develop reaction conditions for the syntheses of [trans-C4F9CF=CFXe]+ salts.

References

3.
Preparation of 1-X-2, 2-Difluoroethenylxenon(II) Tetrafluoroborates [CF2=CXXe][BF4]
Frohn H., Bardin V.V.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2003
6.
Polyfluoroorganotrifluoroborates and -difluoroboranes: interesting materials in fluoroorgano and fluoroorgano-element chemistry
Abo-Amer A., Adonin N.Y., Bardin V.V., Fritzen P., Frohn H., Steinberg C.
Journal of Fluorine Chemistry, 2004
9.
(Fluoroorgano)fluoroboranes and -fluoroborates
Frohn H.-., Bardin V.V.
Journal of Organometallic Chemistry, 2001