Home / Publications / Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8

Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8

Alexey Anatol'evich Goryunkov 1
Alexey Anatol'evich Goryunkov
Evgeniy Ivanovich Dorozhkin 1
Evgeniy Ivanovich Dorozhkin
Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
Daria Vladimirovna Ignat'eva 1
Daria Vladimirovna Ignat'eva
Stanislav Mikhailovich Avdoshenko 1
Stanislav Mikhailovich Avdoshenko
Published 2007-03-15
CommunicationVolume 17, Issue 2, 110-112
15
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Goryunkov A. A. et al. Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8 // Mendeleev Communications. 2007. Vol. 17. No. 2. pp. 110-112.
GOST all authors (up to 50) Copy
Goryunkov A. A., Dorozhkin E. I., Tamm N. B., Ignat'eva D. V., Avdoshenko S. M., Sidorov L. N., Troyanov S. I. Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8 // Mendeleev Communications. 2007. Vol. 17. No. 2. pp. 110-112.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2007.03.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.020
TI - Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8
T2 - Mendeleev Communications
AU - Goryunkov, Alexey Anatol'evich
AU - Dorozhkin, Evgeniy Ivanovich
AU - Tamm, Nadezhda Borisovna
AU - Ignat'eva, Daria Vladimirovna
AU - Avdoshenko, Stanislav Mikhailovich
AU - Sidorov, Lev Nikolaevich
AU - Troyanov, Sergey Igorevich
PY - 2007
DA - 2007/03/15
PB - Mendeleev Communications
SP - 110-112
IS - 2
VL - 17
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Goryunkov,
author = {Alexey Anatol'evich Goryunkov and Evgeniy Ivanovich Dorozhkin and Nadezhda Borisovna Tamm and Daria Vladimirovna Ignat'eva and Stanislav Mikhailovich Avdoshenko and Lev Nikolaevich Sidorov and Sergey Igorevich Troyanov},
title = {Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.020},
number = {2},
pages = {110--112},
doi = {10.1016/j.mencom.2007.03.020}
}
MLA
Cite this
MLA Copy
Goryunkov, Alexey Anatol'evich, et al. “Synthesis and molecular structure of 1,6,11,16,18,24,27,36-C60(CF3)8.” Mendeleev Communications, vol. 17, no. 2, Mar. 2007, pp. 110-112. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.020.

Abstract

1,6,11,16,18,24,27,36-C60(CF3)8 was synthesised by a reaction of C60 with CF3I at 420 °C followed by HPLC separation; its molecular structure contains eight CF3 groups attached in a continuous para-para-para-meta-para-meta-para ribbon of seven edge-sharing C6(CF3)2 hexagons on a C60 cage.

References

1.
Production of Perfluoroalkylated Nanospheres from Buckminsterfullerene
Fagan P.J., Krusic P.J., McEwen C.N., Lazar J., Parkert D.H., Herron N., Wasserman E.
Science, 1993
2.
10.1016/j.mencom.2007.03.020_bib2_1
Uzkikh
Dokl. Akad. Nauk, 2001
3.
Unusual addition patterns in trifluoromethylation of [60]fullerene
Darwish A.D., Abdul-Sada A.K., Avent A.G., Lyakhovetsky Y., Shilova E.A., Taylor R.
Organic and Biomolecular Chemistry, 2003
4.
Isolation of C60(CF3)n (n = 2, 4, 6, 8, 10) with high compositional purity
Goryunkov A.A., Kuvychko I.V., Ioffe I.N., Dick D.L., Sidorov L.N., Strauss S.H., Boltalina O.V.
Journal of Fluorine Chemistry, 2003
5.
Synthesis, Characterization, and Theoretical Study of Stable Isomers of C70(CF3)n (n = 2, 4, 6, 8, 10)
Dorozhkin E.I., Ignat'eva D.V., Tamm N.B., Goryunkov A.A., Khavrel P.A., Ioffe I.N., Popov A.A., Kuvychko I.V., Streletskiy A.V., Markov V.Y., Spandl J., Strauss S.H., Boltalina O.V.
Chemistry - A European Journal, 2006
6.
Structure of 1,4,10,19,25,41-C70(CF3)6, isomer with unique arrangement of addends
Dorozhkin E.I., Ignat’eva D.V., Tamm N.B., Vasilyuk N.V., Goryunkov A.A., Avdoshenko S.M., Ioffe I.N., Sidorov L.N., Pattison P., Kemnitz E., Troyanov S.I.
Journal of Fluorine Chemistry, 2006
7.
Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18
Avdoshenko S.M., Goryunkov A.A., Ioffe I.N., Ignat'eva D.V., Sidorov L.N., Pattison P., Kemnitz E., Troyanov S.I.
Chemical Communications, 2006
8.
10.1016/j.mencom.2007.03.020_bib5_1
Kareev
Acta Crystallogr., 2006
9.
Synthesis, Structure, and 19F NMR Spectra of 1,3,7,10,14,17,23,28,31,40-C60(CF3)10
Kareev I.E., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Seppelt K., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2005
10.
10.1016/j.mencom.2007.03.020_bib5_3
Kareev
Acta Crystallogr., 2006
11.
10.1016/j.mencom.2007.03.020_bib5_4
Kareev
Acta Crystallogr., 2006
12.
Selective synthesis of a trifluoromethylated fullerene and the crystal structure of C60(CF3)12.
Troyanov S.I., Dimitrov A., Kemnitz E.
Angewandte Chemie - International Edition, 2006
13.
Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern:  C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6
Kareev I.E., Shustova N.B., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2006
14.
Numbering of Fullerenes (IUPAC Recommendations 2004)
Cozzi F., Powell W.H., Thilgen C.
Pure and Applied Chemistry, 2005
15.
Preparation and characterization of C60Br6 and C60Br8
Birkett P.R., Hitchcock P.B., Kroto H.W., Taylor R., Walton D.R.
Nature, 1992
16.
Bromination of [60]Fullerene. II. Crystal and Molecular Structure of [60]Fullerene Bromides, C60Br6, C60Br8, and C60Br24
Troyanov S.I., Troshin P.A., Boltalina O.V., Kemnitz E.
Fullerenes Nanotubes and Carbon Nanostructures, 2003
17.
Early stages in the addition to C60 to form C60Xn, X=H, F, Cl, Br, CH3, C4H9
Clare B.W., Kepert D.L.
Journal of Molecular Structure THEOCHEM, 2003
18.
General atomic and molecular electronic structure system
Schmidt M.W., Baldridge K.K., Boatz J.A., Elbert S.T., Gordon M.S., Jensen J.H., Koseki S., Matsunaga N., Nguyen K.A., Su S., Windus T.L., Dupuis M., Montgomery J.A.
Journal of Computational Chemistry, 1993
20.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996