Home / Publications / 2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives

2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives

Anna Olegovna Antipova ¹

Anna Olegovna Antipova

Vasily Viktorovich Tumanov ¹

Vasily Viktorovich Tumanov

William Arturovich Smit ¹

William Arturovich Smit

¹ N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2007.03.008

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Published 2007-03-15

Communication , Volume 17, Issue 2, 80-81

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Antipova A. O., Tumanov V. V., Smit W. A. 2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives // Mendeleev Communications. 2007. Vol. 17. No. 2. pp. 80-81.

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TY - JOUR

DO - 10.1016/j.mencom.2007.03.008

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.008

TI - 2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives

T2 - Mendeleev Communications

AU - Antipova, Anna Olegovna

AU - Tumanov, Vasily Viktorovich

AU - Smit, William Arturovich

PY - 2007

DA - 2007/03/15

PB - Mendeleev Communications

SP - 80-81

IS - 2

VL - 17

ER -

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@article{2007_Antipova,

author = {Anna Olegovna Antipova and Vasily Viktorovich Tumanov and William Arturovich Smit},

title = {2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives},

journal = {Mendeleev Communications},

year = {2007},

volume = {17},

publisher = {Mendeleev Communications},

month = {Mar},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.008},

number = {2},

pages = {80--81},

doi = {10.1016/j.mencom.2007.03.008}

}

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Antipova, Anna Olegovna, et al. “2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene as a versatile bis-nucleophilic reagent for the preparation of polyfunctional 1,3-diene derivatives.” Mendeleev Communications, vol. 17, no. 2, Mar. 2007, pp. 80-81. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.008.

Abstract

A new tandem C–C bond forming process has been developed, which utilises silyl-capped dienic bis-nucleophile 3 and various electrophiles under Lewis acid conditions; a short route for synthesis of functionalised 1,6-enynes has been proposed.