Home / Publications / Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study

Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study

Evgeny Aleksandrovich Pidko 1
Evgeny Aleksandrovich Pidko
, 
Rutger A van Santen 1
Rutger A van Santen
10.1016/j.mencom.2007.03.004
Published 2007-03-15
Communication , Volume 17, Issue 2, 68-70
8
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Pidko E. A., van Santen R. A. Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study // Mendeleev Communications. 2007. Vol. 17. No. 2. pp. 68-70.
GOST all authors (up to 50) Copy
Pidko E. A., van Santen R. A. Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study // Mendeleev Communications. 2007. Vol. 17. No. 2. pp. 68-70.
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TY - JOUR
DO - 10.1016/j.mencom.2007.03.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.004
TI - Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study
T2 - Mendeleev Communications
AU - Pidko, Evgeny Aleksandrovich
AU - van Santen, Rutger A
PY - 2007
DA - 2007/03/15
PB - Mendeleev Communications
SP - 68-70
IS - 2
VL - 17
ER -
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@article{2007_Pidko,
author = {Evgeny Aleksandrovich Pidko and Rutger A van Santen},
title = {Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.004},
number = {2},
pages = {68--70},
doi = {10.1016/j.mencom.2007.03.004}
}
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Pidko, Evgeny Aleksandrovich, and Rutger A van Santen. “Activation of light alkanes over Cd2+ ions in ZSM-5 zeolite: a theoretical study.” Mendeleev Communications, vol. 17, no. 2, Mar. 2007, pp. 68-70. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.03.004.

Abstract

A DFT study of ethane activation over cadmium exchanged ZSM-5 zeolite shows that the interaction of C2H6 with the Cd2+ sites results in a strongly perturbed molecular adsorption leading to heterolytic cleavage of the C–H bond with a moderate activation barrier.

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