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Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Albina Ivanovna Mikhaleva 1
Albina Ivanovna Mikhaleva
, 
Nadezhda Victorovna Zorina 1
Nadezhda Victorovna Zorina
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Andrei Valer'evich Afonin 1
Andrei Valer'evich Afonin
, 
Alexander Mikhailovich Vasil'tsov 1
Alexander Mikhailovich Vasil'tsov
10.1016/j.mencom.2007.01.016
Published 2007-01-17
Communication , Volume 17, Issue 1, 40-42
9
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Trofimov B. A. et al. Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene // Mendeleev Communications. 2007. Vol. 17. No. 1. pp. 40-42.
GOST all authors (up to 50) Copy
Trofimov B. A., Schmidt E. Y., Mikhaleva A. I., Zorina N. V., Ushakov I. A., Afonin A. V., Vasil'tsov A. M. Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene // Mendeleev Communications. 2007. Vol. 17. No. 1. pp. 40-42.
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TY - JOUR
DO - 10.1016/j.mencom.2007.01.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.016
TI - Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Schmidt, Elena Yur'evna
AU - Mikhaleva, Albina Ivanovna
AU - Zorina, Nadezhda Victorovna
AU - Ushakov, Igor Alekseevich
AU - Afonin, Andrei Valer'evich
AU - Vasil'tsov, Alexander Mikhailovich
PY - 2007
DA - 2007/01/17
PB - Mendeleev Communications
SP - 40-42
IS - 1
VL - 17
ER -
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@article{2007_Trofimov,
author = {Boris Aleksandrovich Trofimov and Elena Yur'evna Schmidt and Albina Ivanovna Mikhaleva and Nadezhda Victorovna Zorina and Igor Alekseevich Ushakov and Andrei Valer'evich Afonin and Alexander Mikhailovich Vasil'tsov},
title = {Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.016},
number = {1},
pages = {40--42},
doi = {10.1016/j.mencom.2007.01.016}
}
MLA
Cite this
MLA Copy
Trofimov, Boris Aleksandrovich, et al. “Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene.” Mendeleev Communications, vol. 17, no. 1, Jan. 2007, pp. 40-42. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.016.

Abstract

3-Acetylindole oxime reacts with acetylene (KOH/DMSO, 120 °C, 1 h, 20–25 atm) to unexpectedly give 4-methyl-1-vinyl-δ-carboline 2 in 40% yield along with minor product 1-vinyl-3-(1'-vinyl-2'-pyrrolyl)indole 3 (6%).

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