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Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte

Eugenia Viktorovna Starodubtseva 1
Eugenia Viktorovna Starodubtseva
, 
Olga Vasil'evna Turova 1
Olga Vasil'evna Turova
, 
Maksim Gavrilovich Vinogradov 1
Maksim Gavrilovich Vinogradov
, 
Vladimir Alekseevich Ferapontov 1
Vladimir Alekseevich Ferapontov
, 
Ilya Vladimirovich Razmanov 1
Ilya Vladimirovich Razmanov
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
, 
Alexander Sergeevich Kucherenko 1
Alexander Sergeevich Kucherenko
10.1016/j.mencom.2007.01.008
Published 2007-01-17
Communication , Volume 17, Issue 1, 20-21
6
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Starodubtseva E. V. et al. Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte // Mendeleev Communications. 2007. Vol. 17. No. 1. pp. 20-21.
GOST all authors (up to 50) Copy
Starodubtseva E. V., Turova O. V., Vinogradov M. G., Ferapontov V. A., Razmanov I. V., Zlotin S. G., Kucherenko A. S. Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte // Mendeleev Communications. 2007. Vol. 17. No. 1. pp. 20-21.
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TY - JOUR
DO - 10.1016/j.mencom.2007.01.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.008
TI - Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte
T2 - Mendeleev Communications
AU - Starodubtseva, Eugenia Viktorovna
AU - Turova, Olga Vasil'evna
AU - Vinogradov, Maksim Gavrilovich
AU - Ferapontov, Vladimir Alekseevich
AU - Razmanov, Ilya Vladimirovich
AU - Zlotin, Sergei Grigorievich
AU - Kucherenko, Alexander Sergeevich
PY - 2007
DA - 2007/01/17
PB - Mendeleev Communications
SP - 20-21
IS - 1
VL - 17
ER -
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@article{2007_Starodubtseva,
author = {Eugenia Viktorovna Starodubtseva and Olga Vasil'evna Turova and Maksim Gavrilovich Vinogradov and Vladimir Alekseevich Ferapontov and Ilya Vladimirovich Razmanov and Sergei Grigorievich Zlotin and Alexander Sergeevich Kucherenko},
title = {Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte},
journal = {Mendeleev Communications},
year = {2007},
volume = {17},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.008},
number = {1},
pages = {20--21},
doi = {10.1016/j.mencom.2007.01.008}
}
MLA
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Starodubtseva, Eugenia Viktorovna, et al. “Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte.” Mendeleev Communications, vol. 17, no. 1, Jan. 2007, pp. 20-21. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2007.01.008.

Abstract

The asymmetric hydrogenation of methyl levulinate to chiral γ-valerolactone has been performed with the recycling of a RuII–BINAP catalyst deposited on a solid organic polyelectrolyte; enantioselectivity up to 99% ee has been achieved at high conversion of substrate after three recycles of the catalyst.

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Asymmetric Hydrogenation and Catalyst Recycling Using Ionic Liquid and Supercritical Carbon Dioxide
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Journal of the American Chemical Society, 2001
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A novel system consisting of Rh–DuPHOS and ionic liquid for asymmetric hydrogenations
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Enantioselective hydrogenation of ethyl 4-chloro-3-oxobutyrate in solutions of organic salts with recycling of the catalyst Ru-BINAP
Starodubtseva E.V., Vinogradov M.G., Pavlov V.A., Gorshkova L.S., Ferapontov V.A.
Russian Chemical Bulletin, 2004